Iroishi Checker
No. 099 / 141

Blue Fluorite

ブルーフローライト · ぶるーふろーらいと
NaturalBlue
Gemological dataPROPERTIES
Hardness4
Specific gravity3.18
Refractive index1.434
Crystal system等軸晶系
Color rangeCOLOR RANGE

Pale sky-blue to deep cobalt-blue, often with bands. The Castleton Blue John shows characteristic alternating purple, yellow, and pale-blue bands (12 named varieties from the type locality: Treak Cliff Blue, Old Tor Vein, Twelve Vein, Bull Beef, Five Vein, Organ Room, Landscape, and others). Hunan Chinese material is more uniform, deep cobalt-blue.

UV responseFLUORESCENCE
Long-wave
365 nm
Strong blue to violet luorescence' from Stokes's 1852 Cambridge paper; the diagnostic single-test identifier
Short-wave
254 nm
Strong blue to violet ; some specimens show after SW-UV excitation
Typical inclusionsINCLUSIONS
  • planes visible as four sets of parallel reflective surfaces at the octahedral angles — diagnostic at 10×
  • Colour banding and zoning from differential trace-element substitution during crystal growth
  • egative crystals showing cubic faces)
  • nclusions in dark or 'oil-fluorite' material from Wölsendorf and the Illinois-Kentucky district
  • nclusions of barite, galena, sphalerite (from epithermal-vein paragenesis)
  • Triangular 'pits' on damaged surfaces — diagnostic feature
Optical characterOPTICAL TRAITS
  • Refractive index 1.434 — one of the lowest among gem minerals, calibration reference for the low-RI end of the refractometer
  • Singly refractive (isotropic cubic ) — no
  • Perfect octahedral in four directions — produces characteristic triangular faces
  • Mohs 4 — the standard reference for hardness 4 on the Mohs scale
  • Specific gravity 3.18
  • Strong blue-to-violet luorescence' itself was coined for this mineral
  • 0.007 — low , no 'fire' compared with diamond (0.044)
What to look forID POINTS
  1. 01Strong blue or violet under 365 nm UV — diagnostic single-test identifier separating from all other blue gem materials
  2. 02Refractive index 1.434 on the refractometer — diagnostic for fluorite (overlap only with opal at 1.430–1.460 and the polymer-acrylic at 1.49–1.50, both easily separated by other tests)
  3. 03Mohs 4 — scratches with a Mohs-5 knife edge; aquamarine (Mohs 7.5) and blue topaz (Mohs 8) are dramatically harder
  4. 04Four-direction octahedral visible as four sets of parallel reflective planes — diagnostic versus calcite's three-direction rhombohedral
  5. 05Specific gravity 3.18 — separates from blue calcite (2.69–2.71) and blue topaz (3.49–3.57)
  6. 06Cubic-system isotropic single refraction — separates from doubly refractive blue calcite, blue topaz, and aquamarine
Stones it gets mistaken forSIMILAR STONES
Aquamarine
Aquamarine
アクアマリン
Aquamarine (Be₃Al₂Si₆O₁₈ beryl, Mohs 7.5, SG 2.68–2.74, RI 1.567–1.583, doubly refractive uniaxial negative, hexagonal , no ) versus blue fluorite (Mohs 4, SG 3.18, RI 1.434, singly refractive isotropic cubic, strong blue-violet LW-UV , perfect octahedral ). The hardness gap (Mohs 7.5 versus 4) and the refractive-index gap (1.567–1.583 versus 1.434) are decisive — fluorite is unambiguously separated by refractometer and scratch test. The alone is diagnostic: aquamarine is inert while fluorite shows the characteristic strong blue-violet response under 365 nm UV that gave its name.
Blue Topaz
Blue Topaz
ブルートパーズ
Blue topaz (Al₂SiO₄(F,OH)₂, Mohs 8, SG 3.49–3.57, RI 1.609–1.643, doubly refractive orthorhombic, perfect basal in one direction, weak-to-inert ) versus blue fluorite (Mohs 4, SG 3.18, RI 1.434, singly refractive isotropic cubic, perfect octahedral in four directions, strong blue-violet LW-UV ). Topaz is dramatically harder (Mohs 8 versus 4) and shows distinct doubly refractive on the polariscope; fluorite shows the characteristic isotropic dark cross. The refractive-index difference (1.609–1.643 versus 1.434) is unambiguous on the refractometer. The four-direction octahedral of fluorite versus the one-direction basal of topaz is decisive on visual inspection. Most commercial blue topaz is irradiation-treated colourless topaz (the standard market product since the 1970s GIA-validated treatment); blue fluorite colour is generally natural.
Care & handlingCARE
  • Mohs 4 — easily scratched, store separately from harder gemstones
  • Perfect octahedral in four directions — extreme caution against impact; even minor knocks will fracture along planes
  • No ultrasonic cleaning, no steam cleaning — vibration and heat fracture the
  • Avoid temperatures above 200°C — colour bleaches reversibly above 350°C
  • Acid-sensitive surface (HF will dissolve the species; even dilute HCl etches the polish)
  • Limit jewelry use to pendants, earrings, and brooches; rings are inappropriate due to fragility
Market notesMARKET
PRICE RANGE

Wholesale blue-fluorite cabochons and beads at $2–$30 per piece; faceted Hunan Chinese gemstones at $5–$50 per carat for clean medium-saturation material; Castleton Blue John authenticated ornamental pieces (small bowls, candle holders) at $200–$3,000 per piece direct from the two operating caverns; antique Boulton-Watt 18th–19th-century Blue John vases reach $10,000–$200,000+ at major auction (Sotheby's, Christie's English furniture sales). Mont Blanc pink fluorite (not blue, but the same species) at the same price tier or higher for exhibition crystals. Collector-grade Okorusu Namibian blue octahedra at $50–$2,000 per crystal cluster.

Note: Disclosure as 'natural fluorite' is required; heat-treatment to deepen colour or bleach unwanted purple is occasionally encountered and must be disclosed under FTC Jewelry Guides §23.22 and CIBJO Blue Book. The Castleton Blue John material is sold only as authenticated ornamental and lapidary pieces from the two operating caverns under English Heritage conservation oversight — most retail 'Blue John' jewelry outside Castleton uses Chinese or Mexican material with imitation banding. The Hunan Chinese gem-cutting rough is the price reference for faceted material. Beware ultrasonic and steam cleaning which fracture the perfect octahedral cleavage; beware temperature-induced colour bleaching above 350°C; beware acid which etches the surface. The collector specimen market values undamaged crystal habit (cubic, octahedral, or 'twinned penetration cubes') over colour saturation.

BackgroundBACKGROUND

Fluorite (CaF₂) is the calcium-fluoride mineral that crystallizes in the cubic isometric system, producing famous cubic and octahedral crystals. The blue variety derives its colour from a combination of trace Y³⁺/REE substitution and natural radiation-induced colour centres — the same mechanism that produces purple Castleton Blue John and that responds reversibly to heating (above 350°C the colour bleaches). Mohs 4 (the standard Mohs reference for hardness 4), SG 3.18, refractive index 1.434 (one of the lowest among gem minerals — the standard 'low-RI' end of the refractometer calibration range), perfect octahedral in four directions producing characteristic triangular faces visible at 10×. Singly refractive, isotropic. The cubic-system symmetry and the geometry are the classical mineralogy teaching example.

Origin & historyORIGIN & HISTORY

Origins

Castleton, Derbyshire, England — exclusively at Treak Cliff Cavern and Blue John Cavern, the only world localities for the banded purple-blue-yellow ornamental variety known as 'Blue John' (a contraction of the French bleu-jaune). The two operational mines extract approximately 500 kg per year combined, working a vein system in Carboniferous limestone that has been continuously mined since at least the 1760s and possibly since Roman times. Hunan Province, China (post-2010 the dominant world source for clear blue and purple fluorite gem-cutting rough — Yaogangxian and Xianghualing mines), Namibia (Okorusu mine, blue and green octahedra), the United States (the Illinois-Kentucky Fluorspar District at Cave-in-Rock and Rosiclare, supplying the 'Rosiclare blue' octahedron specimens), Mexico (Las Cuevas, San Luis Potosí), Germany (the historic Wölsendorf, Bavaria deposits), and the Alps (Mont Blanc and Argentière, France) are the major modern and historical sources. The Mont Blanc 'pink fluorite' from the Aiguilles Rouges massif is the world's premier collector specimen variety, though pink rather than blue.

History

luorescence' in his 1852 Cambridge paper on the violet-blue luminescence of Castleton fluorspar — the rare instance of a chemical-physical phenomenon being named after the mineral that exemplifies it. The 20th-century decline at Castleton was reversed in the 1960s when small-scale mining at Treak Cliff and Blue John caverns reopened for the souvenir and modern lapidary trade. The Chinese Hunan deposits emerged as the dominant world source for blue and purple gem-cutting rough from c. 2010 onward.

Lore & symbolism

No traditional birthstone designation. In the modern crystal-healing tradition (Melody 1995, Hall 2003), blue fluorite is associated with the throat chakra, mental focus, and stress reduction — the 'Genius Stone' or 'Stone of Discernment' in metaphysical lore. The 18th- and 19th-century English aristocratic association with Castleton Blue John gives the variety a distinctive cultural resonance — owning a Boulton-Watt fluorite vase remains a recognized marker of Georgian-era English country-house heritage. The connection makes blue fluorite a popular specimen for 365 nm UV-torch demonstrations at mineral fairs and museum education programs (Castleton Blue John Cavern offers a UV-tour for visitors).

OBSERVATION TOOLS · 3 ITEMS

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References
最終確認日
2026年4月28日
参 考 文 献

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